Hierarchical mesoporous silica templated by the combination of fine emulsion and micelles

Highlights

• Mixed Organized Molecular Systems are formed by the mixture of Kolliphor and P123 templates.

• Hierarchical mesoporous silicas obtained by combining fine emulsion and micelles.

• Porosity features controlled by the weight.

• Ratios between fine emulsion and P123 micelles lower than 5/5 lead to dual mesoporous silica.

• Fine emulsion drives the porosity for ratios higher than 5/5.

Concentrated emulsions have been widely considered as templates for the preparation of macroporous structures. Replacing concentrated emulsions by fine ones should rather lead to materials having large mesopores. However, fine emulsions were barely investigated for this purpose. On the other hand, mesostructured silica SBA-15 can be prepared from Pluronic P123 micelles according to the cooperative templating mechanism. Starting from mixture of fine emulsion and Pluronic P123 micelles, it is expected to obtain silicas with a controlled hierarchical mesoporosity.

The fine emulsion has been formulated from the Kolliphor/Myristate/Water system. To get informations concerning the degree of compatibility between the two surfactants, which can affect the formation of the porous materials, the Kolliphor/P123/water system has been investigated in detail. The structural parameters of the mixed liquid crystal phases have been determined and the mixed micellar structure has been investigated by SAXS.

The hierarchical porous silicas have been synthetized combining fine emulsion and Pluronic micellar solution. The materials porosity features strongly depend on the weight proportion between the fine emulsion and the P123 micelles. If this proportion is lower than 5/5, mesoporous silicas present a dual mesoporosity. By contrast, by increasing this proportion the mesopore size distribution only shows large mesopores.

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Article Information: Author links open overlay panelClaudia Violeta Cervantes-Martinez, Marie-José Stébé, Mélanie Emo, Bénédicte Lebeau, Jean-Luc Blin; Microporous and Mesoporous Materials, 2020.